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Principles of the Living Matter A001809 2024-25

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The reaction for the synthesis of ammonia is exothermic:   N2 (g)  +  3 H2 (g)  ↔ 2 NH3 (g)  

Predict where does the reaction shift and what happens to Keq after the following changes: (2 pts)

ChangeReaction shiftKeq
Addition of N2 at constant temperature  
Decrease of volume at constant temperature
Increase of temperature
Addition of gaseous HCl at constant temperature

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A mass of 12.0 g of acetic acid (Ka = 1.80 · 10-5) is solubilized in 50.0 mL of water at T=298 K. Then, the resulting solution is diluted to 4.00 L at the same temperature. Calculate the final pH: (1 pt)

Final pH:   

How many moles of calcium hydroxide are necessary to completely neutralize the acid? (1 pt)

Moles of calcium hydroxide:   

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Consider the following substances: Li2

O,

Si, H

2SO4. Which type of solid do they originate under the appropriate conditions of T and p, respectively? (1.5 pts)

Li2O
Si
H2SO4

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Consider the following molecules: HClO2, PCl5, NO2-.

Predict their respective shape and the most suitable hybrid orbital for the central atom. (1.5 pts)

Molecule           ShapeHybrid orbital
HClO2 
PCl5 
NO2- 

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The reaction 3 Al (s) + 3 NH4ClO(s) → Al2O3 (s) + AlCl

(g) + 3 NO (g) +

6 H

2

O (g) has been used in the Space Shuttle rocket boosters. Calculate the pressure

exerted by the gases developed at 800 K when the reaction is made to occur in a

3.00 L closed cylinder into which 0.500 kg of Al powder and 1.50 kg of NH

4ClO4

have been introduced.

(2 pts)

Pressure:    atm

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The pKa of methanethiol (CH3SH) is 13, the pKof methanol is 17. Which consequence does it have?

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D-Glucose and D-fructose (see picture for D-fructose) are:

File:D-Fructose.svg - Wikipedia

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Which reagent is required to convert propane into 2-chloropropane?

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What is true about ketones?

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Which is the main product for the following reaction?

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