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The 5 questions below (a. to e.) are related to the following graph. The graph...

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The 5 questions below (a. to e.) are related to the following graph.

The graph below shows the concentrations of the reactants and products for a endothermic reaction under reversible conditions where the reactants and products are all gases.

A concentration versus time graph for a reversible reaction where compound A forms compound B.

Time / minutes[A] / mol L-1[B] / mol L-1
0.000.8100.345
2.00  0.3000.600
6.000.3570.850
10.000.4800.780

 

 

  1. Given the variations of concentration over time depicted in the graph and table above, determine the stoichiometric coefficients for the reversible reaction

    (enter the stoichiometric coefficients as numbers, e.g. if you think the balancing number should be 1 then type "1") [1 mark]

    A (g)  ⇌  B (g)

  2. If, at a certain time, the value of the equilibrium constant, K, was 6.67. What would the value of the equilibrium constant be if all the stoichiometric coefficients for the reaction were halved?  [1 mark]

    (give your answer to 3 significant figures):  

  3. At each of the times labelled "Time(1)" and "Time(2)" a disturbance was made to the reaction mixture.

    1. Determine what disturbance was made at "Time(1)" [0.5 marks]

    2. Determine what disturbance was made at "Time(2)" [0.5 marks]

  4. How will the value of the equilibrium constant at 10 minutes (K10 min) compare to the value of the equilibrium constant at 6 minutes (K6 min) [1 mark]

    The equilibrium constant at 10 minutes will be
    the equilibrium constant at 6 minutes

  5. The enthalpy change, ΔrH, for the forward reaction is +52 kJ mol-1. The temperature of the system at 10 minutes was 298 K. What was the temperature of the system at 6 minutes?  [1 mark]

    (give your answer to 3 significant figures and in units of K, do not type the units in the answer box):  K
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