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General Chemistry for Engineers_ Nhom 02FIE

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14. For the reaction 2A + B <=> 2C the appropriate form for the equilibrium constant expression is:

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5. An equilibrium that strongly favors products has __________

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8. If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________

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47. Which of the following occurs when reactants are added to a chemical reaction in solution or the gas phase at equilibrium?

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The following rate constants were obtained in an experiment in which the decomposition of gaseous N2O5 was studied as a function of temperature. The products were NO2 and NO3.

   T (oC)           k (s-1)       

   47            0,45

   81            7,0

Determine the rate constant (s-1) for this reaction at 149 oC.  

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58. Given: A(s) + B(l) <=> C(g) + D(g) ΔH° = 84.3 kJ.

If the above reactants and products are contained in a closed vessel and the reaction system is at equilibrium, the number of moles of C can be decreased by which of the following? (Note that the reactants are solid and liquid.)

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3. Which of the following are equal for a chemical system at equilibrium?

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The activation energy for the reaction in which CO2 decomposes to CO and a free radical oxygen atom, O, has an activation energy of 37,8 kJ/mol. The frequency factor is 1,6x107s-1. What is the rate constant (s-1) for this reaction at 298 K?

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4. A chemical equilibrium may be established by starting a reaction with __________

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57. Given the following reaction at equilibrium, which of the following alterations will increase the amount (in moles) of SO2Cl2:

SO2(g) + Cl2(g) <=> SO2Cl2(g) ΔH° = -67 kJ

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