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CHEM 1023 WI01-04 General Chemistry 2 2025 Winter

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F=96485 C mol-1,    R=8.314 J mol-1 K-1,      T=298 K

Part A

Using the table below, calculate the equilibrium constant for the electrochemical cell represented by the following line notation:

Cr(s)|Cr3+(aq)||Fe2+(aq)|Fe(s)

Express your answer to two significant figures.

K 

=

Part B

For the reaction above, calculate the standard Gibbs energy change.

Write your answer to three significant figures.

ΔrG° =

kJ/mol

Part C

Based on your answer in Part B, identify the spontaneity of the reaction:

The above redox reaction is

Standard Electrode Potentials at 25ºC      Eº(V)

Ag+(aq)+e

→Ag(s)

0.80

Pb2+(aq)+2e

→Pb(s)

-0.13

Ni2+(aq)+2e

→Ni(s)

-0.23

Co2+(aq)+2e

→Co(s)

-0.28

Cd2+(aq)+2e

→Cd(s)

-0.40

Fe2+(aq)+2e

→Fe(s)

-0.45

Cr3+(aq)+3e

→Cr(s)

-0.73

Zn2+(aq)+2e

→Zn(s)

-0.76

Mn2+(aq)+2e

→Mn(s)

-1.18

Al3+(aq)+3e

→Al(s)

-1.66

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The standard reduction potentials of lithium metal and chlorine gas are as follows:

Li+(aq) + e→ Li(s) 

=−3.04 V

Cl2(g) + 2e→ 2Cl(aq)  E°=

+1.36 V

Part A

Calculate the cell potential of a galvanic cell involving the half-reactions shown above under standard conditions.

Express your answer to two decimal places.

cell =

V

Part B

Calculate the standard Gibbs energy change

of the reaction.

Express your answer to three significant figures.

ΔrG° = kJ/mol

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Which species can oxidize Cd

but not Sn?  

A table of standard electrode potentials is available on Moodle. 

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Examine the following half-reactions and select the strongest reducing agent among the species listed.

Sn2+(aq) + 2e → Sn(s)      E° = -0.14 V

Zn2+(aq) + 2e → Zn(s)

      E° = -0.76 V

Mn2+(aq) + 2e → Mn(s)     E° = –1.18 V

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Part A

Using the table below, calculate the standard cell potential for the following reaction:

     Zn(s)+2Ag+(aq

)→Zn2+(aq)+2Ag(s)

Express your answer to two decimal places.

Eºcell = V

Part B

Determine whether or not the cell reaction above is spontaneous as written, under standard conditions:

Standard Electrode Potentials at 25ºC   Eº (V)

Ag+(aq)+e

→Ag(s)

0.80

Pb2+(aq)+2e

→Pb(s)

-0.13

Ni2+(aq)+2e

→Ni(s)

-0.23

Co2+(aq)+2e

→Co(s)

-0.28

Cd2+(aq)+2e

→Cd(s)

-0.40

Fe2+(aq)+2e

→Fe(s)

-0.45

Cr3+(aq)+3e

→Cr(s)

-0.73

Zn2+(aq)+2e

→Zn(s)

-0.76

Mn2+(aq)+2e

→Mn(s)

-1.18

Al3+(aq)+3e

→Al(s)

-1.66

 

 

 

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What is the IUPAC name for the following compound?

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What is the IUPAC name for the following compound?

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What is the IUPAC name for the following compound?

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What is the IUPAC name for the following compound?

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What is the IUPAC name for the following compound?

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