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CHM1011 - Chemistry I - S1 2025

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Formic acid is the simplest carboxylic acid, HCOOH. It is the cause of pain in bee and ant stings and nearly a million tonnes are made each year because it is a good preservative. In water, formic acid behaves as a weak acid:

HCOOH(aq) + H2O(l)  ⇌  HCOO-(aq) + H3O+(aq)

 

The concentration of formate ions (HCOO-) is increased by adding sodium formate (HCOONa). Which of the statements below is the best explanation of the process of returning to equilibrium after the sodium formate has been added?

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Using the standard entropy values:

                  SO2(g),  So = +248.0 J·mol–1·K–1

                  SO3(g),  So = +256.0 J·mol–1·K–1

                  NO(g),   So = +210.6 J·mol–1·K–1

                  NO2(g),  So = +240.5 J·mol–1·K–1

 

calculate the standard entropy change, ΔSo, for the reaction:

                   NO2(g) + SO2(g)  →  NO(g) + SO3(g)

 

Enter your answer in J·mol-1·K-1 to one decimal place. Do not enter units.

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What condition must be true for a chemical reaction to be spontaneous?

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A spontaneous reaction is always exothermic.

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Which one of the following processes is accompanied by a decrease in entropy of the system?
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Entropy is a measure of:

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The criterion for a spontaneous chemical reaction is
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Which one of the following reactions is accompanied by an increase in entropy?
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Using the following So values 

H2(g),      S= 130.58 J·mol-1·K-1

C2H4(g),  S= 219.4 J·mol-1·K-1

C2H6(g),  S= 229.5 J·mol-1·K-1

calculate ΔSo in J mol-1 K-1 for the reaction below.

C2H4(g) + H2(g) → C2H6(g)

Enter your answer in the box.  Do not enter units.

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Conclusion

You should finish your report with a short statement commenting on what was achieved, and what the final numerical result/s were. Think of it as a spoiler for your whole lab report! Your conclusion should answer all parts of your aim.

For example:

If the aim is: Determine the concentration of Vitamin C in a fruit juice via a redox titration against N-bromosuccinimide.

The conclusion might be: Berri orange juice (2000 μL aliquots, in triplicate) was titrated against a 0.104 M solution of N-bromosuccinimide. The concentration of Vitamin C in the fruit juice was determined to be 55.0 mg/L.

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